Development Status of Copper Electroplating Filling Technology in Through Glass Via for 3D Interconnections

Zhi-Jing Ji , Hui-Qin Ling , Pei-Lin Wu , Rui-Yi Yu , Da-Quan Yu , Ming Li

Journal of Electrochemistry ›› 2022, Vol. 28 ›› Issue (6) : 2104461 -2104461.

PDF (3380KB)
Journal of Electrochemistry ›› 2022, Vol. 28 ›› Issue (6) :2104461 -2104461. DOI: 10.13208/j.electrochem.210446
OReviews
research-article
Development Status of Copper Electroplating Filling Technology in Through Glass Via for 3D Interconnections
Author information +
History +
PDF (3380KB)

Abstract

With the slow development of Moore's Law, the high density and miniaturization of microelectronic devices put forward higher requirements for advanced packaging technology. As a key technology in 2.5D/3D packaging, interposer technology has been extensively studied. According to different interposer materials, it is mainly divided into organic interposer, silicon interposer and glass interposer. Compared with the through silicon via (TSV) interconnection, the through glass via (TGV) interposer has received extensive attention in the 2.5D/3D advanced packaging field for its advantages of excellent high-frequency electrical characteristics, simple process, low cost, and adjustable coefficient of thermal expansion (CTE). However, the thermal conductivity of glass (about 1 W·m-1·K-1) is much lower than that of silicon (about 150 W·m-1·K-1), thus, the glass interposer has serious heat dissipation problems. In order to obtain a high-quality TGV interposer, not only an efficient and low-cost via preparation process, but also a defect-free filling process is required. The challenges faced by glass interposer is mainly concentrated in these two aspects. This review firstly introduces the preparation process of TGV, such as ultra-sonic drilling (USD), ultra-sonic high speed drilling (USHD), wet etching, deep reactive ion etching (DRIE), photosensitive glass, laser etching, laser induced deep etching (LIDE), etc. Then it summarizes the defect-free filling of TGV, and outlines several filling mechanisms and some current filling processes of TGV, such as bottom-up filling mechanisms, butterfly filling mechanisms and conformal filling mechanisms. Among the filling mechanisms of the above three filling methods, the filling method of bottom-up is the most studied one, and many scholars have given relevant explanations. Currently, the main ones that are commonly used are the diffusion-consumption mechanism, curvature enhanced adsorbate coverage mechanism (CEAC), convection dependent adsorption mechanism (CDA), and S-shaped negative differential resistance theory. In the process of TGV filling, the type and concentration of base bath, additives and electroplating process will affect the filling status of TGV. At present, the constant current plating mode is most commonly used in the process of TGV filling. Then the research progress of TGV electroplating additives is introduced, including the action mechanism of typical additives and the current research status of some new additives. Through glass via technology can be filled with the synergistic action of accelerators, suppressors and levelers. Finally, the practical application of TGV is briefly reviewed, for example, glass interposer is used in 3D integrated passive device (IPD), embedded glass fan-out technology (eGFO), integrated antenna packaging, micro-electro-mechanical system (MEMS), multi-chip module packaging, as well as the applications in the field of optical integration technology.

Keywords

interposer / through glass via / filling mechanisms / filling process, additives

Cite this article

Download citation ▾
Zhi-Jing Ji, Hui-Qin Ling, Pei-Lin Wu, Rui-Yi Yu, Da-Quan Yu, Ming Li. Development Status of Copper Electroplating Filling Technology in Through Glass Via for 3D Interconnections. Journal of Electrochemistry, 2022, 28(6): 2104461-2104461 DOI:10.13208/j.electrochem.210446

登录浏览全文

4963

注册一个新账户 忘记密码

References

[1]

Sukumaran V, Kumar G, Ramachandran K, Suzuki Y, Demir K, Sato Y, Seki T, Sundaram V, Tummala R R. Design, fabrication, and characterization of ultrathin 3-D glass interposers with through-package-vias at same pitch as TSVs in silicon[J]. IEEE Trans. Compon. Pack. Manuf. Technol., 2014, 4(5): 786-795.

[2]

Hsieh M C, Kang K T, Choi H C, Kim Y C.International Microsystems Packaging Assembly and Circuits Technol- ogy Conference, Taipei, October 26-28, 2016[C]. Piscat-away: IEEE, 2016.

[3]

Hsieh M, Lin S, Hsu I, Chen C Y, Cho N J. 2017 21st Eu-ropean Microelectronics and Packaging Conference (EM-PC) & Exhibition, Warsaw, September 10-13, 2017[C]. Piscataway: IEEE, 2018.

[4]

Usman A, Shah E, Satishprasad N B, Chen J L, Bohle-mann S A, Shami S H, Eftekhar A A, Adibi A. Interposer technologies for high-performance applications[J]. IEEE Trans. Compon. Pack. Manuf. Technol., 2017, 7 (6): 819-828.

[5]

Kuramochi S, Kudo H, Akazawa M, Mawatari H, Tanaka M, Fukuoka Y. 2016 6th Electronic System-Integration Technology Conference (ESTC), Grenoble, September 13-15, 2016[C]. Piscataway: IEEE, 2016.

[6]

Kuramochi S, Koiwa S, Nagano H, Iida J, Akazawa M, Mawatari H, Suzuki K, Fukuoka Y. 2016 Pan Pacific Mi-croelectronics Symposium (Pan Pacific), Big Island, HI, January 25-28, 2016[C]. Piscataway: IEEE, 2016.

[7]

Ohtsuki C, Kokubo T, Yamamuro T. Mechanism of ap-atite formation on CaO-SiO2-P2O5 glasses in a simulated body fluid[J]. J. Non-Cryst. Solids, 1992, 143(1): 84-92.

[8]

Töpper M, Ndip I, Erxleben R, Brusberg L, Nissen N, Schröder H, Yamamoto H, Todt G, Reichl H. 2010 Proceed-ings 60th Electronic Components and Technology Confer-ence, Las Vegas, NV, June 1-4, 2010[C]. Piscataway: IEEE, 2010.

[9]

Ogutu P G. Hybrid metallization of glass and superconfor-mal filling of through glass vias for interposer application[D]. Binghamton: State University of New York at Bing-hamton, 2015.

[10]

Sukumaran V, Bandyopadhyay T, Sundaram V, Tummala R. Low-cost thin glass interposers as a superior alterna-tive to silicon and organic interposers for packaging of 3-D ICs[J]. IEEE Trans. Compon. Pack. Manuf. Technol., 2012, 2(9): 1426-1433.

[11]

Garrou P, Koyanagi M, Ramm P. Handbook of 3D inte-gration: volume 3-3D process technology[M]. Germany: Wiley-VCH Verlag GmbH & Co. KGaA, 2014.

[12]

Wang Q W(王强文), Guo Y H(郭育华), Liu J J(刘建军), Wang Y L(王运龙). High heat dissipation performance of the TGV interposer[J]. Micronanoelectron. Technol.(微纳电子技术), 2021, 58(2): 177-183.

[13]

Zheng L, Zhang Y, Zhang X, Bakir M S. 2015 IEEE 65th Electronic Components and Technology Conference, San Diego, CA, May 26-29, 2015[C]. Piscataway: IEEE, 2015.

[14]

Lai W C, Chuang H H, Tsai C H, Yeh E H, Lin C H, Peng T H, Yen L J, Liao W S, Hung J N, Sheu C C, Yu C H, Wang C T, Yee K C, Yu D. 2013 IEEE International Electron Devices Meeting, Washington, DC, December 9-11, 2013[C]. Piscataway: IEEE, 2014.

[15]

LPKF. Through glass via (TGV) wafer[EB/OL]. (2018-02-05). https://www.vitrion.com/en/applications/through-glass-vias-tgv/

[16]

Ostholt R, Ambrosius N, Kruger R A.Proceedings of the 5th Electronics System-integration Technology Confer-ence (ESTC), Helsinki, September 16-18, 2014[C]. Piscat-away: IEEE, 2014.

[17]

Shacham-Diamand Y, Osaka T, Datta M, Ohba T. Ad-vanced nanoscale ULSI interconnects: Fundamentals and applications[M]. New York: Springer, 2009.

[18]

Su W, Yao L B, Yang F, Li P Y, Chen J, Liang L F. Elec-troless plating of copper on surface-modified glass sub-strate[J]. Appl. Surf. Sci., 2011, 257(18): 8067-8071.

[19]

Huang T, Sundaram V, Raj P M, Sharma H, Tummala R. 2014 IEEE 64th Electronic Components and Technology Conference (ECTC), Orlando, FL, May 27-30, 2014[C]. Piscataway: IEEE, 2014.

[20]

Xie D(谢迪), Li H(李浩), Wang C X(王从香), Cui K(崔凯), Hu Y F(胡永芳). Study on technology of through glass via for 3D integration package[J]. Electronics & Packag-ing(电子与封装), 2021, 21(7): 20-25.

[21]

Wang B K, Chen Y A, Shorey A, Piech G. 2012 7th In-ternational Microsystems, Packaging, Assembly and Cir-cuits Technology Conference, Taipei, October 24-26, 2012[C]. Piscataway: IEEE, 2013.

[22]

West A C, Mayer S, Reid J. A superfilling model that predicts bump formation[J]. Electrochem. Solid State Lett., 2001, 4(7): C50-C53.

[23]

Moffat T P, Wheeler D, Kim S K, Josell D. Curvature en-hanced adsorbate coverage mechanism for bottom-up su-perfilling and bump control in damascene processing[J]. Electrochim. Acta, 2007, 53(1): 145-154.

[24]

Dow W P, Yen M Y, Liao S Z, Chiu Y D, Huang H C. Filling mechanism in microvia metallization by copper electroplating[J]. Electrochim. Acta, 2008, 53(28): 8228-8237.

[25]

Moffat T P, Josell D. Extreme bottom-up superfilling of through-silicon-vias by damascene processing: suppres-sor disruption, positive feedback and turing patterns[J]. J. Electrochem. Soc., 2012, 159(4): D208-D216.

[26]

Dow W P, Chen H H, Yen M Y, Chen W H, Hsu K H, Chuang P Y, Ishizuka H, Sakagawa N, Kimizuka R. Through-hole filling by copper electroplating[J]. J. Elec-trochem. Soc., 2008, 155(12): D750-D757.

[27]

Dow W P, Liu D H, Lu C W, Chen C H, Yan J J, Huang S M. Through-hole filling by copper electroplating using a single organic additive[J]. Electrochem. Solid State Lett., 2011, 14(1): D13-D15.

[28]

Ogutu P, Fey E, Dimitrov N. Superconformal filling of through vias in glass interposers[J]. ECS Electrochem. Lett., 2014, 3(8): D30-D32.

[29]

Ogutu P, Fey E, Dimitrov N. Superconformal filling of high aspect ratio through glass vias (TGV) for interposer applications using TNBT and NTBC additives[J]. J. Ele-ctrochem. Soc., 2015, 162(9): D457-D464.

[30]

Fey E, Li J X, Dimitrov N. Fast and cost-effective super-conformal filling of high aspect ratio through glass vias using MTT additive[J]. J. Electrochem. Soc., 2017, 164(6): D289-D296.

[31]

Chang Y H, Tseng P L, Lin J C, Chen J C, Huang M C, Lin H Y, Pollard S, Mazumder P. Communication-de-fect-free filling of high aspect ratio through vias in ultra-thin glass[J]. J. Electrochem. Soc., 2018, 166(1): D3155-D3157.

[32]

Wu S S, Ling H Q, Xie Y T, Li M, Yu D Q. 2020 21st International Conference on Electronic Packaging Tech-nology (ICEPT), Guangzhou,August 12-15, 2020[C]. Pis-cataway: IEEE, 2020.

[33]

Xiao H B, Wang F L, Wang Y, He H, Zhu W H. Effect of ultrasound on copper filling of high aspect ratio through-silicon via (TSV)[J]. J. Electrochem. Soc., 2017, 164(4): D126-D129.

[34]

Wang F L, Zeng P, Wang Y, Ren X Y, Xiao H B, Zhu W H. High-speed and high-quality TSV filling with the di-rect ultrasonic agitation for copper electrodeposition[J]. Microelectron. Eng., 2017, 180: 30-34.

[35]

Xie Y T(谢怡彤), Wu S S(吴珊珊), Li M(李明).一种填充玻璃转接板通孔的双电源双阳极电镀装置及方法:中国, 202010042855.6[P]. 2020-05-15.

[36]

Kim I R, Park J K, Chu Y C, Jung J P. High speed Cu filling into TSV by pulsed current for 3 dimensional chip stacking[J]. Korean J. Met. Mater., 2010, 48(7): 667-673.

[37]

Hong S C, Lee W G, Kim W J, Kim J H, Jung J P. Re-duction of defects in TSV filled with Cu by high-speed 3-step PPR for 3D Si chip stacking[J]. Microelectron. Reliab., 2011, 51(12): 2228-2235.

[38]

Chen Y(陈杨), Cheng J(程骄), Wang C(王翀), He W(何为), Zhu K(朱凯), Xiao D J(肖定军). The influence fac-tors of through-hole copper plating at high current densi-ty[J]. Plat. Finish.(电镀与精饰), 2015, 37(8): 23-27.

[39]

Lai Z Q(赖志强). Research and application of high speed copper electroplating for the interconnection micro-holes of printed circuit board[D]. Chengdu: University of Elec-tronic Science and Technology of China(电子科技大学), 2020.

[40]

Xu L H, Dixit P, Miao J, Pang J H L, Zhang X, Tu K N, Preisser R. Through-wafer electroplated copper intercon-nect with ultrafine grains and high density of nanotwins[J]. Appl. Phys. Lett., 2007, 90(3): 033111.

[41]

Jin S, Seo S, Wang G, Too B. Electrodeposition of nan-otwin Cu by pulse current for through-Si-via (TSV) pro-cess[J]. J. Nanosci. Nanotechnol., 2016, 16(5): 5410-5414.

[42]

Sun F L, Liu Z Q, Li C F, Zhu Q S, Zhang H, Suganuma K. Bottom-up electrodeposition of large-scale nanotwinn-ed copper within 3D through silicon via[J]. Materials, 2018, 11(2): 319.

[43]

Guymon C G, Harb J N, Rowley R L, Wheeler D R. MP-SA effects on copper electrodeposition investigated by molecular dynamics simulations[J]. J. Chem. Phys., 2008, 128(4): 044717.

[44]

Peykova M, Michailova E, Stoychev D, Milchev A. Gal-vanostatic studies of the nucleation and growth kinetics of copper in the presence of surfactants[J]. Electrochim. Acta, 1995, 40(16): 2595-2601.

[45]

Stoychev D, Vitanova I, Bujukliev R, Petkova N, Popova I, Pojarliev I. Effect of some dialkyl-, diaryl-, and diary-lalkyl-disulphide derivatives on copper electrodeposition[J]. J. Appl. Electrochem., 1992, 22(10): 978-986.

[46]

Hai N T M, Huynh T T M, Fluegel A, Arnold M, Mayer D, Reckien W, Bredow T, Broekmann P. Competitive anion/anion interactions on copper surfaces relevant for Damascene electroplating[J]. Electrochim. Acta, 2012, 70: 286-295.

[47]

Moffat T P, Baker B, Wheeler D, Josell D. Accelerator aging effects during copper electrodeposition[J]. Electro-chem. Solid State Lett., 2003, 6(4): C59-C62.

[48]

Kim S K, Kim J J. Superfilling evolution in Cu electrode-position: dependence on the aging time of the accelerator[J]. Electrochem. Solid State Lett., 2004, 7(9): C98-C100.

[49]

Tan M, Guymon C, Wheeler D R, Harb J N. The role of SPS, MPSA, and chloride in additive systems for copper electrodeposition[J]. J. Electrochem. Soc., 2007, 154(2): D78-D81.

[50]

Pasquale M A, Gassa L M, Arvia A J. Copper electrode-position from an acidic plating bath containing accelerat-ing and inhibiting organic additives[J]. Electrochim. Ac-ta, 2008, 53(20): 5891-5904.

[51]

Kim J J, Kim S K, Kim Y S. Catalytic behavior of 3-mer-capto-1-propane sulfonic acid on Cu electrodeposition and its effect on Cu film properties for CMOS device metallization[J]. J. Electroanal. Chem., 2003, 542: 61-66.

[52]

Li L Q(李立清), An W J(安文娟), Wang Y(王义). Ac-tion mechanism of MPS and chloride ions in electroplat-ing copper microvia filling[J]. Surf. Technol.(表面技术), 2018, 47(5): 122-129.

[53]

Dow W P, Chiu Y D, Yen M Y. Microvia filling by Cu electroplating over a Au seed layer modified by a disul-fide[J]. J. Electrochem. Soc., 2009, 156(4): D155-D167.

[54]

Yokoi M, Konishi S, Hayashi T. Adsorption behavior of polyoxyethyleneglycole on the copper surface in an acid copper sulfate bath[J]. Denki Kagaku, 1984, 52(4): 218-223.

[55]

Feng Z V, Li X, Gewirth A A. Inhibition due to the inter-action of polyethylene glycol, chloride, and copper in plating baths: a surface-enhanced Raman study[J]. J. Phys. Chem. B, 2003, 107(35): 9415-9423.

[56]

Willey M J, West A C. Microfluidic studies of adsorption and desorption of polyethylene glycol during copper electrodeposition[J]. J. Electrochem. Soc., 2006, 153(10): C728-C734.

[57]

Josell D, Moffat T P. Superconformal copper deposition in through silicon vias by suppression-breakdown[J]. J. Electrochem. Soc., 2018, 165(2): D23-D30.

[58]

Gallaway J W, West A C. PEG, PPG, and their triblock copolymers as suppressors in copper electroplating[J]. J. Electrochem. Soc., 2008, 155(10): D632-D639.

[59]

Gallaway J W, Willey M J, West A C. Copper filling of 100 nm trenches using PEG, PPG, and a triblock copoly-mer as plating suppressors[J]. J. Electrochem. Soc., 2009, 156(8): D287-D295.

[60]

Josell D, Moffat T P. Extreme bottom-up filling of through silicon vias and damascene trenches with gold in a sulfite electrolyte[J]. J. Electrochem. Soc., 2013, 160(12): D3035-D3039.

[61]

Xiao N(肖宁). Study on microvia filling performances and action mechanisms of EPE inhibitors in copper elec-troplating process[D]. Harbin:Harbin Institute of Tech-nology(哈尔滨工业大学), 2013.

[62]

Li Y B, Wang W, Li Y L. Adsorption behavior and relat-ed mechanism of Janus Green B during copper via-filling process[J]. J. Electrochem. Soc., 2009, 156(4): D119-D124.

[63]

Li J, Zhou G Y, Hong Y, Wang C, He W, Wang S X, Chen Y M, Wen Z S, Wang Q Y. Copolymer of pyrrole and 1,4-butanediol diglycidyl as an efficient additive leveler for through-hole copper electroplating[J]. ACS Omega, 2020, 5(10): 4868-4874.

[64]

Wang X, Zhang S T, Chen S J, Tan B C, Guo H L, Wang Y, Qiang Y J, Fu S L, Wen Y N. Effects of 2,2-dithiodip-yridine as a leveler for through-holes filling by co pper electroplating[J]. J. Electrochem. Soc., 2019, 166(13): D660-D668.

[65]

Chen B A, Xu J, Wang L M, Song L F, Wu S Y. Synthe-sis of quaternary ammonium salts based on diketopy-rrolopyrroles skeletons and their applications in copper electroplating[J]. ACS Appl. Mater. Interfaces, 2017, 9(8): 7793-7803.

[66]

Haba T, Ikeda K, Uosaki K. Electrochemical and in situ SERS study of the role of an inhibiting additive in selective electrodeposition of copper in sulfuric acid[J]. Electrochem. Commun., 2019, 98: 19-22.

[67]

Liu X D(刘筱笛), Ming P M(明平美), Zhang J Z(张峻中), Li R Q(李润清), Zhao X M(赵西梅). Research and development of the purification technology of electroplat-ing solution[J]. Plat. Finish.(电镀与精饰), 2017, 39(12): 20-24.

[68]

Liu C(刘成), Huang T L(黄廷林), Zhao J W(赵建伟). Removal effect of organic matters of different MW dur-ing the process of coagulation and adsorption of pow-dered activated carbon[J]. Water Purif. Technol.(净水技术), 2006, 25(1): 31-33.

[69]

Liu W(刘伟), Gao S B(高书宝), Wu D(吴丹), Cai R H (蔡荣华), Huang X P(黄西平), Zhang Q(张琦). The pro-cess of membrane extraction separation technique and applications[J]. J. Salt Sci. Chem. Ind.(盐科学与化工), 2013, 42(11): 26-31.

[70]

Tummala R, Sundaram V. Impact of 3D ICs with TSV is profound but complex and costly-is there a better way[J]. Chip Scale Review, 2011, 8: 31-32.

[71]

Chen L(陈力), Yang X F(杨晓锋), Yu D Q(于大全). De-velopment of through glass via technology[J]. Electronics & Packaging(电子与封装), 2021, 21(4): 5-17.

[72]

Lee T C, Chang Y S, Hsu C M, Hsieh S C, Lee P N, Hsieh Y C, Wang L C, Zhang L J. 2017 IEEE 67th Electronic Components and Technology Conference (ECTC), Orlan-do, FL, May 30- June 2, 2017[C]. Piscataway: IEEE, 2017.

[73]

Watanabe A O, Ali M, Zhang R, Ravichandran S, Kaku-tani T, Raj P M, Tummala R R, Swaminathan M. 2020 IEEE 70th Electronic Components and Technology Con-ference (ECTC), Orlando, FL, June 3-30, 2020[C]. Pis-cataway: IEEE, 2020.

[74]

Yu T, Zhang X D, Chen L, Ren X L, Duan Z M, Yu D Q. 2020 IEEE 70th Electronic Components and Technology Conference, Orlando, FL, June 3-30, 2020[C]. Piscataway: IEEE, 2020.

[75]

Lee J Y, Lee S W, Lee S K, Park J H. 2013 IEEE 26th Proceedings IEEE Micro Electro Mechanical Systems (MEMS), Taipei, January 20-24, 2013[C]. Piscataway: IEEE, 2013.

[76]

Ma S L, Ren K L, Xia Y M, Yan J, Luo R F, Cai H, Jin Y F, Ma M J, Jin Z H, Chen J. 2016 17th International Con-ference on Electronic Packaging Technology (ICEPT), Wuhan,August 16-19, 2016[C]. Piscataway: IEEE, 2016.

[77]

Iwia T, Sakai T, Mizutani D, Sakuyama S, Iida K, Inaba T, Fujisaki H, Miyazawa Y. 2018 IEEE 68th Electronic Components and Technology Conference (ECTC), San Diego, CA, May 29-June 1, 2018[C]. Piscataway: IEEE, 2018.

[78]

Iwia T, Sakai T, Mizutani D, Sakuyama S, Iida K, Inaba T, Fujisaki H, Tamura A, Miyazawa Y. 2019 IEEE 69th Electronic Components and Technology Conference (ECTC), Las Vegas, NV, May 28-31, 2019[C]. Piscataway: IEEE, 2019.

PDF (3380KB)

690

Accesses

0

Citation

Detail

Sections
Recommended

/