Ordering Degree Regulation of Pt₂NiCo Intermetallics for Efficient Oxygen Reduction Reaction

Abstract

Alloying transition metals with Pt is an effective strategy for optimizing Pt-based catalysts toward the oxygen reduction reaction (ORR). Atomic ordered intermetallic compounds (IMC) provide unique electronic and geometrical effects as well as stronger intermetallic interactions due to the ordered arrangement of metal atoms, thus exhibiting superior electrocatalytic activity and durability. However, quantitatively analyzing the ordering degree of IMC and exploring the correlation between the ordering degree and ORR activity remains extremely challenging. Herein, a series of ternary Pt₂NiCo intermetallic catalysts (o-Pt₂NiCo) with different ordering degree were synthesized by annealing temperature modulation. Among them, the o-Pt₂NiCo which annealed at 800 °C for two hours exhibits the highest ordering degree and the optimal ORR activity, which the mass activity of o-Pt₂NiCo is 1.8 times and 2.8 times higher than that of disordered Pt₂NiCo alloy and Pt/C. Furthermore, the o-Pt₂NiCo still maintains 70.8% mass activity after 30,000 potential cycles. Additionally, the ORR activity test results for Pt₂NiCo IMC with different ordering degree also provide a positive correlation between the ordering degree and ORR activity. This work provides a prospective design direction for ternary Pt-based electrocatalysts.

Keywords

Fuel cell / Oxygen reduction reaction / Electrocatalysis / Intermetallic compound / Ordering degree

Supporting Information

Additional data, detailed experimental procedures, and supplementary figures are available free of charge on the journal’s website at https://jelectrochem.xmu.edu.cn/journal/.

Acknowledgements

This work was supported by the National Natural Science Foundation (22279036) and the Innovation and Talent Recruitment Base of New Energy Chemistry and Device (B21003).

Conflict of Interest

The authors declare no conflict of interest.

Data availability

Data will be made available on request.

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