A Room-Temperature Chloride-Conducting Metal-Organic Crystal [Al(DMSO)<sub>6</sub>]Cl<sub>3</sub> for Potential Solid-State Chloride-Shuttle Batteries

Bing Wu; Jan Luxa; Jiř&iacute; Šturala; Shuangying Wei; Luk&aacute;š Děkanovsk&yacute;; Abhilash Karuthedath Parameswaran; Min Li; Zdenek Sofer

doi:10.1002/eem2.12530

Energy & Environmental Materials ›› 2024, Vol. 7 ›› Issue (1) : 12530. DOI: 10.1002/eem2.12530

RESEARCH ARTICLE

A Room-Temperature Chloride-Conducting Metal-Organic Crystal [Al(DMSO)₆]Cl₃ for Potential Solid-State Chloride-Shuttle Batteries

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Abstract

The growing demand for substitutes of lithium chemistries in battery leads to a surge in budding novel anion-based electrochemical energy storage, where the chloride ion batteries (CIBs) take over the role. The application of CIBs is limited by the dissolution and side reaction of chloride-based electrode materials in a liquid electrolyte. On the flipside, its solid-state electrolytes are scarcely reported due to the challenge in realizing fast Cl^— conductivity. The present study reports [Al(DMSO)₆]Cl₃, a solid-state metal-organic material, allows chloride ion transfer. The strong Al-Cl bonds in AlCl₃ are broken down after coordinating of Al³⁺ by ligand DMSO, and Cl^— in the resulting compound is weakly bound to complexions [Al(DMSO)₆]³⁺, which may facilitate Cl^— migration. By partial replacement of Cl^— with $P F 6 −$ , the room-temperature ionic conductivity of as-prepared electrolyte is increased by one order of magnitude from 2.172 × 10^–5 S cm^–1 to 2.012 × 10^–4 S cm^–1. When they are assembled with Ag (anode)/Ag-AgCl (cathode) electrode system, reversible electrochemical redox reactions occur on both sides, demonstrating its potential for solid-state chloride ion batteries. The strategy by weakening the bonding interaction using organic ligands between Cl^— and central metallic ions may provide new ideas for developing solid chloride-ion conductors.

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[Al(DMSO)₆]Cl₃ / chloride-ion batteries / ionic conductivity / metal-organic / solid-state electrolytes

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Bing Wu, Jan Luxa, Jiří Šturala, Shuangying Wei, Lukáš Děkanovský, Abhilash Karuthedath Parameswaran, Min Li, Zdenek Sofer. A Room-Temperature Chloride-Conducting Metal-Organic Crystal [Al(DMSO)₆]Cl₃ for Potential Solid-State Chloride-Shuttle Batteries. Energy & Environmental Materials, 2024, 7(1): 12530 https://doi.org/10.1002/eem2.12530

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