Alkali Metal Ion Substituted Carboxymethyl Cellulose as Anode Polymeric Binders for Rapidly Chargeable Lithium-Ion Batteries

Seoungwoo Byun; Zhu Liu; Dong Ok Shin; Kyuman Kim; Jaecheol Choi; Youngjoon Roh; Dahee Jin; Seungwon Jung; Kyung-Geun Kim; Young-Gi Lee; Stefan Ringe; Yong Min Lee

doi:10.1002/eem2.12509

Energy & Environmental Materials ›› 2024, Vol. 7 ›› Issue (1) : 12509 DOI: 10.1002/eem2.12509

RESEARCH ARTICLE

Alkali Metal Ion Substituted Carboxymethyl Cellulose as Anode Polymeric Binders for Rapidly Chargeable Lithium-Ion Batteries

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Abstract

The increasing demand for short charging time on electric vehicles has motivated realization of fast chargeable lithium-ion batteries (LIBs). However, shortening the charging time of LIBs is limited by Li⁺ intercalation process consisting of liquid-phase diffusion, de-solvation, SEI crossing, and solid-phase diffusion. Herein, we propose a new strategy to accelerate the de-solvation step through a control of interaction between polymeric binder and solvent-Li⁺ complexes. For this purpose, three alkali metal ions (Li⁺, Na⁺, and K⁺) substituted carboxymethyl cellulose (Li-, Na-, and K-CMC) are prepared to examine the effects of metal ions on their performances. The lowest activation energy of de-solvation and the highest chemical diffusion coefficient were observed for Li-CMC. Specifically, Li-CMC cell with a capacity of 3 mAh cm^-2 could be charged to >95% in 10 min, while a value above >85% was observed after 150 cycles. Thus, the presented approach holds great promise for the realization of fast charging.

Keywords

de-solvation / digital twins / fast charging / graphite anodes / polymeric binders

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Seoungwoo Byun, Zhu Liu, Dong Ok Shin, Kyuman Kim, Jaecheol Choi, Youngjoon Roh, Dahee Jin, Seungwon Jung, Kyung-Geun Kim, Young-Gi Lee, Stefan Ringe, Yong Min Lee. Alkali Metal Ion Substituted Carboxymethyl Cellulose as Anode Polymeric Binders for Rapidly Chargeable Lithium-Ion Batteries. Energy & Environmental Materials, 2024, 7(1): 12509 DOI:10.1002/eem2.12509

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