Nonconventional aggregation-induced emission polysiloxanes: Structures, characteristics, and applications

Abstract

Nonconventional luminescent materials have been rising stars in organic luminophores due to their intrinsic characteristics, including water-solubility, biocompatibility, and environmental friendliness and have shown potential applications in diverse fields. As an indispensable branch of nonconventional luminescent materials, polysiloxanes, which consist of electron-rich auxochromic groups, have exhibited outstanding photophysical properties due to the unique silicon atoms. The flexible Si-O bonds benefit the aggregation, and the empty 3d orbitals of Si atoms can generate coordination bonds including N → Si and O → Si, altering the electron delocalization of the material and improving the luminescent purity. Herein, we review the recent progress in luminescent polysiloxanes with different topologies and discuss the challenges and perspectives. With an emphasis on the driving force for the aggregation and the mechanism of tuned emissions, the role of Si atoms played in the nonconventional luminophores is highlighted. This review may provide new insights into the design of nonconventional luminescent materials and expand their further applications in sensing, biomedicine, lighting devices, etc.

Keywords

aggregation-induced emission / molecular structure / nonconventional luminescent polymer / photoluminescence property / polysiloxane

RIGHTS & PERMISSIONS

2023 The Authors. Aggregate published by South China University of Technology; AIE Institute and John Wiley & Sons Australia, Ltd.