Triazine-based multicomponent metallacages with tunable structures for SO₂ selective capture and conversion

Abstract

The design of novel materials for sulfur dioxide (SO₂) capture and conversion with considerable efficiency under mild conditions is of great significance for human health and environmental protection yet highly challenging. Herein, we report a series of triazine-based multicomponent metallacages via coordination-driven self-assembly of 2,4,6-tri(4-pyridyl)-1,3,5-triazine, cis-Pt(PEt₃)₂(OTf)2 and different tetracarboxylic ligands. As the increase of the length of the tetracarboxylates, the structures of the metallacages change from pyramids to extended octahedrons. Owing to their N-rich structure, these metallacages are further used for selective SO₂ capture, showing good adsorption capacity and remarkable SO₂/CO₂ selectivity in ambient conditions, suggesting their potential applications toward real flue gas desulfurization. The metallacages are further employed for the conversion of SO₂ into value-added compounds, showing exceptional efficiency even dilute SO₂ is used as the reactant. This study represents a type of structure-tunable triazinebased metallacages for SO₂ capture and conversion, which will pave the way on the applications of metal-organic complexes for gas adsorption.

Keywords

multicomponent metallacages / self-assembly / SO ₂ adsorption / SO ₂ conversion / tunable structures

References

[1] C. K. Baker, M. H. Unsworth, P. Greenwood, Nature 1982, 299, 149.

[2] M. R. Taylor, E. S. Rubin, D. A. Hounshell, Environ. Sci. Technol. 2003, 37, 4527.

[3] M. M. M. F. Jion, J. N. Jannat, M. Y. Mia, M. A. Ali, M. S. Islam, S. M. Ibrahim, S. C. Pal, A. Islam, A. Sarker, G. Malafaia, M. Bilal, A. R. M. T. Islam, Sci. Total. Environ. 2023, 876, 162851.

[4] D. Zheng, J. Yu, J. Wu, Angew. Chem. Int. Ed. 2016, 55, 11925.

[5] Z. Li, L. Jiao, Y. Sun, Z. He, Z. Wei, W. Liao, Angew. Chem. Int. Ed. 2020, 59, 7266.

[6] Y. Cheng, Y. Ying, S. Japip, S. Jiang, T. Chung, S. Zhang, D. Zhao, Adv. Mater. 2018, 30, 1802401.

[7] C. Gu, N. Hosono, J. Zheng, Y. Sato, S. Kusaka, S. Sakaki, S. Kitagawa, Science 2019, 363, 387.

[8] W. Sun, Nat. Nanotechnol. 2021, 16, 1054.

[9] C. J. Doonan, D. J. Tranchemontagne, T. G. Glover, J. R. Hunt, O. M. Yaghi, Nat. Chem. 2010, 2, 235.

[10] Y. Ying, S. Peh, H. Yang, Z. Yang, D. Zhao, Adv. Mater. 2022, 34, 2104946.

[11] T. Hasell, M. Miklitz, A. Stephenson, M. A. Little, S. Y. Chong, R. Clowes, L. Chen, D. Holden, G. A. Tribello, K. E. Jelfs, A. I. Cooper, J. Am. Chem. Soc. 2016, 138, 1653.

[12] C. A. Rowland, G. R. Lorzing, A. J. Gosselin, B. A. Trump, G. P. A. Yap, C. M. Brown, E. D. Bloch, J. Am. Chem. Soc. 2018, 140, 11153.

[13] A. Schoedel, M. Li, D. Li, M. O’Keeffe, O. M. Yaghi, Chem. Rev. 2016, 116, 12466.

[14] A. J. Howarth, Y. Liu, P. Li, Z. Li, T. C. Wang, J. T. Hupp, O. K. Farha, Nat. Rev. Mater. 2016, 1, 15018.

[15] K. L. Kollmannsberger, L. Kronthaler, J. R. Jinschek, R. A. Fischer, Chem. Soc. Rev. 2022, 51, 9933.

[16] X. Han, S. Yang, M. Schröder, Nat. Rev. Chem. 2019, 3, 108.

[17] T. Islamoglu, Z. Chen, M. C. Wasson, C. T. Buru, K. O. Kirlikovali, U. Afrin, M. R. Mian, O. K. Farha, Chem. Rev. 2020, 120, 8130.

[18] F. Chen, D. Lai, L. Guo, J. Wang, P. Zhang, K. Wu, Z. Zhang, Q. Yang, Y. Yang, B. Chen, Q. Ren, Z. Bao, J. Am. Chem. Soc. 2021, 143, 9040.

[19] W. Li, J. Li, T. D. Duong, S. A. Sapchenko, X. Han, J. D. Humby, G. F. S. Whitehead, I. J. Victórica-Yrezábal, I. Silva, P. Manuel, M. D. Frogley, G. Cinque, M. Schröder, S. Yang, J. Am. Chem. Soc. 2022, 144, 13196.

[20] A. J. Rieth, A. M. Wright, M. Dincă, Nat. Rev. Mater. 2019, 4, 708.

[21] M. R. Tchalala, P. M. Bhatt, K. N. Chappanda, S. R. Tavares, K. Adil, Y. Belmabkhout, A. Shkurenko, A. Cadiau, N. Heymans, G. De Weireld, G. Maurin, K. N. Salama, M. Eddaoudi, Nat. Commun. 2019, 10, 1328.

[22] P. Brandt, S. Xing, J. Liang, G. Kurt, A. Nuhnen, O. Weingart, C. Janiak, ACS Appl. Mater. Inter. 2021, 13, 29137.

[23] Y. Zhang, P. Zhang, W. Yu, J. Zhang, J. Huang, J. Wang, M. Xu, Q. Deng, Z. Zeng, S. Deng, ACS Appl. Mater. Inter. 2019, 11, 10680.

[24] S. Xing, J. Liang, P. Brandt, F. Schäfer, A. Nuhnen, T. Heinen, I. Boldog, J. Möllmer, M. Lange, O. Weingart, C. Janiak, Angew. Chem. Int. Ed. 2021, 60, 17998.

[25] S. Yang, J. Sun, A. J Ramirez-Cuesta, S. K. Callear, W. I. F. David, D. P. Anderson, R. Newby, A. J. Blake, J. E. Parker, C. C. Tang, M. Schröder, Nat. Chem. 2012, 4, 887.

[26] Y. Inokuma, M. Kawano, M. Fujita, Nat. Chem. 2011, 3, 349.

[27] G. H. Clever, P. Punt, Acc. Chem. Res. 2017, 50, 2233.

[28] S. Chakraborty, G. R. Newkome, Chem. Soc. Rev. 2018, 47, 3991.

[29] Y. Sun, C. Chen, J. Liu, P. J. Stang, Chem. Soc. Rev. 2020, 49, 3889.

[30] Y. Sun, P. J. Stang, Aggregate 2021, 2, e94.

[31] C. T. McTernan, J. A. Davies, J. R. Nitschke, Chem. Rev. 2022, 122, 10393.

[32] L. S. Lisboa, J. A. Findlay, L. J. Wright, C. G. Hartinger, J. D. Crowley, Angew. Chem. Int. Ed. 2020, 59, 11101.

[33] P. Howlader, E. Zangrando, P. S. Mukherjee, J. Am. Chem. Soc. 2020, 142, 9070.

[34] H. Sepehrpour, W. Fu, Y. Sun, P. J. Stang, J. Am. Chem. Soc. 2019, 141, 14005.

[35] C. M. Hong, R. G. Bergman, K. N. Raymond, F. D. Toste, Acc. Chem. Res. 2018, 51, 2447.

[36] R. Saha, B. Mondal, P. S. Mukherjee, Chem. Rev. 2022, 122, 12244.

[37] A. J. Gosselin, C. A. Rowland, E. D. Bloch, Chem. Rev. 2020, 120, 8987.

[38] E. Martínez-Ahumada, D. He, V. Berryman, A. López-Olvera, M. Hernandez, V. Jancik, V. Martis, M. A. Vera, E. Lima, D. J. Parker, A. I. Cooper, I. A. Ibarra, M. Liu, Angew. Chem. Int. Ed. 2021, 60, 17556.

[39] N. K. Gupta, A. López-Olvera, E. González-Zamora, E. Martínez-Ahumada, I. A. Ibarra, Chempluschem 2022, 87, e202200006.

[40] S. J. Tan, D. D. Dob, J. W. Chew, Phys. Chem. Chem. Phys. 2020, 22, 21463.

[41] D. D. Miller, S. S. C. Chuang, J. Phys. Chem. C 2015, 119, 6713.

[42] S. J Valencia-Loza, A. López-Olvera, E. Martínez-Ahumada, D. Martínez-Otero, I. A. Ibarra, V. Jancik, E. G. Percástegui, ACS Appl. Mater. Inter. 2021, 13, 18658.

[43] E. Martínez-Ahumada, A. López-Olvera, P. Carmona-Monroy, H. Díaz-Salazar, M. H. Garduño-Castro, J. L. Obeso, C. Leyva, A. Martínez, M. Hernández-Rodríguez, D. Solis-Ibarra, I. A. Ibarra, Dalton Trans. 2022, 51, 18368.

[44] M. Fujita, D. Oguro, M. Miyazawa, H. Oka, K. Yamaguchi, K. Ogura, Nature 1995, 378, 469.

[45] L. Cai, S. Li, D. Yan, L. Zhou, F. Guo, Q. Sun, J. Am. Chem. Soc. 2018, 140, 4869.

[46] S. Li, L. Cai, M. Hong, Q. Chen, Q. Sun, Angew. Chem. Int. Ed. 2022, 61, e202204732.

[47] M. Yoshizawa, M. Tamura, M. Fujita, Science 2006, 312, 251.

[48] Y. Hou, Z. Zhang, S. Lu, J. Yuan, Q. Zhu, W. Chen, S. Ling, X. Li, Y. Zheng, K. Zhu, M. Zhang, J. Am. Chem. Soc. 2020, 142, 18763.

[49] C. Mu, Z. Zhang, Y. Hou, H. Liu, L. Ma, X. Li, S. Ling, G. He, M. Zhang, Angew. Chem. Int. Ed. 2021, 60, 12293.

[50] Y. Zheng, Z. Zhao, M. Wang, K. Ghosh, J. B. Pollock, T. R. Cook, P. J. Stang, J. Am. Chem. Soc. 2010, 132, 16873.

[51] G. Zhang, M. Mastalerz, Chem. Soc. Rev. 2014, 43, 1934.

[52] J. Koo, I. Kim, Y. Kim, D. Cho, I. Hwang, R. D. Mukhopadhyay, H. Song, Y. H. Ko, A. Dhamija, H. Lee, W. Hwang, S. Kim, M. Baik, K. Kim, Chem 2020, 6, 3374.

[53] K. Chi, C. Addicott, M. Moon, H. J. Lee, S. C. Yoon, P. J. Stang, J. Org. Chem. 2006, 71, 6662.

[54] G. Zhang, B. Hua, A. Dey, M. Ghosh, B. A. Moosa, N. M. Khashab, Acc. Chem. Res. 2021, 54, 155.

[55] J. S. Wright, A. J. Metherell, W. M. Cullen, J. R. Piper, R. Dawson, M. D. Ward, Chem. Commun. 2017, 53, 4398.

[56] C. Mellot-Draznieks, C. Serre, S. Surblé, N. Audebrand, G. Férey, J. Am. Chem. Soc. 2005, 127, 16273.

[57] X. Cui, Q. Yang, L. Yang, R. Krishna, Z. Zhang, Z. Bao, H. Wu, Q. Ren, W. Zhou, B. Chen, H. Xing, Adv. Mater. 2017, 29, 1606929.

[58] S. Chen, Y. Wu, W. Zhang, S. Wang, T. Yan, S. He, B. Yang, H. Ma, Chem. Eng. J. 2022, 429, 132480.

[59] H. Woolven, C. González-Rodríguez, I. Marco, A. Thompson, M. Willis, Org. Lett. 2011, 13, 4876.

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