Catalytic steam reforming of tar for enhancing hydrogen production from biomass gasification: a review

Abstract

Presently, the global search for alternative renewable energy sources is rising due to the depletion of fossil fuel and rising greenhouse gas (GHG) emissions. Among alternatives, hydrogen (H₂) produced from biomass gasification is considered a green energy sector, due to its environmentally friendly, sustainable, and renewable characteristics. However, tar formation along with syngas is a severe impediment to biomass conversion efficiency, which results in process-related problems. Typically, tar consists of various hydrocarbons (HCs), which are also sources for syngas. Hence, catalytic steam reforming is an effective technique to address tar formation and improve H₂ production from biomass gasification. Of the various classes in existence, supported metal catalysts are considered the most promising. This paper focuses on the current researching status, prospects, and challenges of steam reforming of gasified biomass tar. Besides, it includes recent developments in tar compositional analysis, supported metal catalysts, along with the reactions and process conditions for catalytic steam reforming. Moreover, it discusses alternatives such as dry and autothermal reforming of tar.

Keywords

hydrogen / biomass gasification / tar / steam reforming / catalyst

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Acknowledgments

This work was financially supported by the University Teknologi Malaysia through Research University Grant (GUP Tier 1: 20H52) and by the Universiti Malaysia Perlis through Fundamental Research Grant Scheme (FRGS 9003-00764).

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