Interface engineering for enhancing electrocatalytic oxygen evolution reaction of CoS/CeO₂ heterostructures

Abstract

To realize renewable energy conversion, it is important to develop low-cost and high-efficiency electrocatalyst for oxygen evolution reaction. In this communication, a novel bijunction CoS/CeO₂ electrocatalyst grown on carbon cloth is prepared by the interface engineering. The interface engineering of CoS and CeO₂ facilitates a rapid charge transfer from CeO₂ to CoS. Such an electrocatalyst exhibits outstanding electrocatalytic activity with a low overpotential of 311 mV at 10 mA∙cm⁻² and low Tafel slope of 76.2 mV∙dec^–1, and is superior to that of CoS (372 mV) and CeO₂ (530 mV) counterparts. And it has long-term durability under alkaline media.

Key words： interface engineering; CoS/CeO₂; electrodeposition; electrocatalyst; oxygen evolution reaction

Electronic Supplementary Material

Supplementary material is available in the online version of this article at http://dx.doi.org/10.1007/s11705-021-2062-x and is accessible for authorized users.

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