Metal phosphonate-derived cobalt/nickel phosphide@N-doped carbon hybrids as efficient bifunctional oxygen electrodes for Zn−air batteries

PDF(3110 KB)
PDF(3110 KB)
Frontiers of Chemical Science and Engineering ›› 2022, Vol. 16 ›› Issue (9) : 1367-1376. DOI: 10.1007/s11705-022-2153-3
RESEARCH ARTICLE

作者信息 +

Metal phosphonate-derived cobalt/nickel phosphide@N-doped carbon hybrids as efficient bifunctional oxygen electrodes for Zn−air batteries

Author information +
History +

Abstract

The exploration of efficient bifunctional electrocatalysts for oxygen reduction reaction and oxygen evolution reaction is pivotal for the development of rechargeable metal–air batteries. Transition metal phosphides are emerging as promising catalyst candidates because of their superb activity and low cost. Herein, a novel metal phosphonate-derived cobalt/nickel phosphide@N-doped carbon hybrid was developed by a carbothermal reduction of cobalt/nickel phosphonate hybrids with different Co/Ni molar ratios. The metal phosphonate derivation method achieved an intimately coupled interaction between metal phosphides and a heteroatom-doped carbon substrate. The resultant Co2P/Ni3P@NC-0.2 enables an impressive electrocatalytic oxygen reduction reaction activity, comparable with those of state-of-the-art Pt/C catalysts in terms of onset potential (0.88 V), 4e selectivity, methanol tolerance, and long-term durability. Moreover, remarkable oxygen evolution reaction activity was also observed in alkaline conditions. The high activity is ascribed to the N-doping, abundant accessible catalytic active sites, and the synergistic effect among the components. This work not only describes a high-efficiency electrocatalyst for both oxygen reduction reaction and oxygen evolution reaction, but also highlights the application of metal phosphonate hybrids in fabricating metal phosphides with tunable structures, which is of great significance in the energy conversion field.

Keywords

metal phosphonate / cobalt/nickel phosphide / N-doped carbon / oxygen electrochemistry / Zn−air battery

引用本文

导出引用
. . Frontiers of Chemical Science and Engineering. 2022, 16(9): 1367-1376 https://doi.org/10.1007/s11705-022-2153-3

参考文献

[1]
Zhang R Q, Ma A, Liang X, Zhao L M, Zhao H, Yuan Z Y. Cobalt nanoparticle decorated N-doped carbons derived from a cobalt covalent organic framework for oxygen electrochemistry. Frontiers of Chemical Science and Engineering, 2021, 15( 6): 1550– 1560
CrossRef ADS Google scholar
[2]
Wang F M, Zhao H M, Ma Y R, Yang Y, Li B, Cui Y Y, Guo Z Y, Wang L. Core-shell-structured Co@Co4N nanoparticles encapsulated into MnO-modified porous N-doping carbon nanocubes as bifunctional catalysts for rechargeable Zn−air batteries. Journal of Energy Chemistry, 2020, 50 : 52– 62
CrossRef ADS Google scholar
[3]
Zhao C X, Liu J N, Wang J, Ren D, Li B Q, Zhang Q. Recent advances of noble-metal-free bifunctional oxygen reduction and evolution electrocatalysts. Chemical Society Reviews, 2021, 50( 13): 7745– 7778
CrossRef ADS Google scholar
[4]
Zhang J T, Zhao Z H, Xia Z H, Dai L M. A metal-free bifunctional electrocatalyst for oxygen reduction and oxygen evolution reactions. Nature Nanotechnology, 2015, 10( 5): 444– 452
CrossRef ADS Google scholar
[5]
Cao R G, Lee J S, Liu M L, Cho J. Recent progress in non-precious catalysts for metal−air batteries. Advanced Energy Materials, 2012, 2( 7): 816– 829
CrossRef ADS Google scholar
[6]
Guo Y Y, Yuan P F, Zhang J N, Xia H C, Cheng F Y, Zhou M F, Li J, Qiao Y Y, Mu S C, Xu Q. Co2P-CoN double active centers confined in N-doped carbon nanotube: heterostructural engineering for trifunctional catalysis toward HER, ORR, OER, and Zn−air batteries driven water splitting. Advanced Functional Materials, 2018, 28( 51): 1805641
CrossRef ADS Google scholar
[7]
Wang H T, Wang W, Xu Y Y, Asif M, Liu H F, Xia B Y. Ball-milling synthesis of Co2P nanoparticles encapsulated in nitrogen doped hollow carbon rods as efficient electrocatalysts. Journal of Materials Chemistry A, 2017, 5( 33): 17563– 17569
CrossRef ADS Google scholar
[8]
Zhao H, Yuan Z Y. Transition metal-phosphorus-based materials for electrocatalytic energy conversion reactions. Catalysis Science & Technology, 2017, 7( 2): 330– 357
CrossRef ADS Google scholar
[9]
Gagnon K J, Perry H P, Clearfield A. Conventional and unconventional metal-organic frameworks based on phosphonate ligands: MOFs and UMOFs. Chemical Reviews, 2012, 112( 2): 1034– 1054
CrossRef ADS Google scholar
[10]
Zhao H, Yuan Z Y. Design strategies of transition-metal phosphate and phosphonate electrocatalysts for energy-related reactions. ChemSusChem, 2021, 14( 1): 130– 149
CrossRef ADS Google scholar
[11]
Lv X W, Weng C C, Zhu Y P, Yuan Z Y. Nanoporous metal phosphonate hybrid materials as a novel platform for emerging applications: a critical review. Small, 2021, 17( 22): 2005304
CrossRef ADS Google scholar
[12]
Zhao H, Weng C C, Ren J T, Ge L, Liu Y P, Yuan Z Y. Phosphonate-derived nitrogen-doped cobalt phosphate/carbon nanotube hybrids as highly active oxygen reduction reaction electrocatalysts. Chinese Journal of Catalysis, 2020, 41( 2): 259– 267
CrossRef ADS Google scholar
[13]
Chen L, Ren J T, Wang Y S, Tian W W, Gao L J, Yuan Z Y. Organic−inorganic cobalt-phosphonate-derived hollow cobalt phosphate spherical hybrids for highly efficient oxygen evolution. ACS Sustainable Chemistry & Engineering, 2019, 7( 15): 13559– 13568
CrossRef ADS Google scholar
[14]
Zhou T H, Du Y H, Wang D P, Yin S M, Tu W G, Chen Z, Borgna A, Xu R. Phosphonate-based metal-organic framework derived Co−P−C hybrid as an efficient electrocatalyst for oxygen evolution reaction. ACS Catalysis, 2017, 7( 9): 6000– 6007
CrossRef ADS Google scholar
[15]
Jiao J Q, Pan Y, Wang B, Yang W J, Liu S J, Zhang C. Melamine-assisted pyrolytic synthesis of bifunctional cobalt-based core–shell electrocatalysts for rechargeable zinc−air batteries. Journal of Energy Chemistry, 2021, 53 : 364– 371
CrossRef ADS Google scholar
[16]
Ren J T, Wang Y S, Chen L, Gao L J, Tian W W, Yuan Z Y. Binary FeNi phosphides dispersed on N,P-doped carbon nanosheets for highly efficient overall water splitting and rechargeable Zn−air batteries. Chemical Engineering Journal, 2020, 389 : 124408
CrossRef ADS Google scholar
[17]
Lv X W, Hu Z P, Chen L, Ren J T, Liu Y P, Yuan Z Y. Organic−inorganic metal phosphonate-derived nitrogen-doped core−shell Ni2P nanoparticles supported on Ni foam for efficient hydrogen evolution reaction at all pH values. ACS Sustainable Chemistry & Engineering, 2019, 7( 15): 12770– 12778
CrossRef ADS Google scholar
[18]
Lv X W, Xu W S, Tian W W, Wang H Y, Yuan Z Y. Activity promotion of core and shell in multifunctional core−shell Co2P@NC electrocatalyst by secondary metal doping for water electrolysis and Zn−air batteries. Small, 2021, 17( 38): 2101856
CrossRef ADS Google scholar
[19]
Li D, Baydoun H, Verani C N, Brock S L. Efficient water oxidation using CoMnP nanoparticles. Journal of the American Chemical Society, 2016, 138( 12): 4006– 4009
CrossRef ADS Google scholar
[20]
Mendoza-Garcia A, Zhu H Y, Yu Y S, Li Q, Zhou L, Su D, Kramer M J, Sun S H. Controlled anisotropic growth of Co−Fe−P from Co−Fe−O nanoparticles. Angewandte Chemie International Edition, 2015, 54( 33): 9642– 9645
CrossRef ADS Google scholar
[21]
Liang X, Zheng B, Chen L, Zhang J, Zhuang Z, Chen B. MOF-derived formation of Ni2P−CoP bimetallic phosphides with strong interfacial effect toward electrocatalytic water splitting. ACS Applied Materials & Interfaces, 2017, 9( 27): 23222– 23229
CrossRef ADS Google scholar
[22]
Lv X W, Tian W W, Liu Y P, Yuan Z Y. Well-defined CoP/Ni2P nanohybrids encapsulated in a nitrogen-doped carbon matrix as advanced multifunctional electrocatalysts for efficient overall water splitting and zinc−air batteries. Materials Chemistry Frontiers, 2019, 3( 11): 2428– 2436
CrossRef ADS Google scholar
[23]
Zhao H, Weng C C, Hu Z P, Ge L, Yuan Z Y. CdS-polydopamine-derived N,S-codoped hierarchically porous carbons as highly active electrocatalyst for oxygen reduction. ACS Sustainable Chemistry & Engineering, 2017, 5( 11): 9914– 9922
CrossRef ADS Google scholar
[24]
Tang J, Liu J, Li C L, Li Y Q, Tade M O, Dai S, Yamauchi Y. Synthesis of nitrogen-doped mesoporous carbon spheres with extra-large pores through assembly of diblock copolymer micelles. Angewandte Chemie International Edition, 2015, 54( 2): 588– 593
CrossRef ADS Google scholar
[25]
Kudin K N, Ozbas B, Schniepp H C, Prud’homme R K, Aksay I A, Car R. Raman spectra of graphite oxide and functionalized graphene sheets. Nano Letters, 2008, 8( 1): 36– 41
CrossRef ADS Google scholar
[26]
Lv X W, Liu Y P, Tian W W, Gao L J, Yuan Z Y. Aluminum and phosphorus codoped “superaerophobic” Co3O4 microspheres for highly efficient electrochemical water splitting and Zn−air batteries. Journal of Energy Chemistry, 2020, 50 : 324– 331
CrossRef ADS Google scholar
[27]
Wang X S, Vasiliff A, Jiao Y, Zheng Y, Qiao S Z. Electronic and structural engineering of carbon-based metal-free electrocatalysts for water splitting. Advanced Materials, 2019, 31( 13): 1803625
CrossRef ADS Google scholar
[28]
Hu L, Hu Y W, Liu R, Mao Y C, Balogun M S, Tong Y X. Co-based MOF-derived Co/CoN/Co2P ternary composite embedded in N- and P-doped carbon as bifunctional nanocatalysts for efficient overall water splitting. International Journal of Hydrogen Energy, 2019, 44( 23): 11402– 11410
CrossRef ADS Google scholar
[29]
Xu K, Sun Y Q, Sun Y M, Zhang Y Q, Jia G C, Zhang Q H, Gu L, Li S Z, Li Y, Fan H J. Yin−Yang harmony: metal and nonmetal dual-doping boosts electrocatalytic activity for alkaline hydrogen evolution. ACS Energy Letters, 2018, 3( 11): 2750– 2756
CrossRef ADS Google scholar
[30]
You B, Jiang N, Sheng M, Bhushan M W, Sun Y. Hierarchically porous urchin-like Ni2P superstructures supported on nickel foam as efficient bifunctional electrocatalysts for overall water splitting. ACS Catalysis, 2016, 6( 2): 714– 721
CrossRef ADS Google scholar
[31]
Borghei M, Laocharoen N, Kibena-Põldsepp E, Johansson L S, Campbell J, Kauppinen E, Tammeveski K, Rojas O J, Porous N. P-doped carbon from coconut shells with high electrocatalytic activity for oxygen reduction: alternative to Pt−C for alkaline fuel cells. Applied Catalysis B: Environmental, 2017, 204 : 394– 402
CrossRef ADS Google scholar
[32]
Huang S, Meng Y, Cao Y, He S, Li X, Tong S, Wu M. N-, O- and P-doped hollow carbons: metal-free bifunctional electrocatalysts for hydrogen evolution and oxygen reduction reactions. Applied Catalysis B: Environmental, 2019, 248 : 239– 248
CrossRef ADS Google scholar
[33]
Zhuang M H, Ou X W, Dou Y B, Zhang L L, Zhang Q C, Wu R Z, Ding Y, Shao M H, Luo Z T. Polymer-embedded fabrication of Co2P nanoparticles encapsulated in N,P-doped graphene for hydrogen generation. Nano Letters, 2016, 16( 7): 4691– 4698
CrossRef ADS Google scholar
[34]
Das D, Nanda K K. One-step, integrated fabrication of Co2P nanoparticles encapsulated N, P dual-doped CNTs for highly advanced total water splitting. Nano Energy, 2016, 30 : 303– 311
CrossRef ADS Google scholar
[35]
Qin Q, Jang H, Li P, Yuan B, Liu X, Cho J. A tannic acid-derived N-, P-codoped carbon-supported iron-based nanocomposite as an advanced trifunctional electrocatalyst for the overall water splitting cells and zinc−air batteries. Advanced Energy Materials, 2019, 9( 5): 1803312
CrossRef ADS Google scholar
[36]
Zhang M, Dai Q, Zheng H, Chen M, Dai L. Novel MOF-derived Co@N−C bifunctional catalysts for highly efficient Zn–air batteries and water splitting. Advanced Materials, 2018, 30( 10): 1705431
CrossRef ADS Google scholar
[37]
Zhao H, Yuan Z Y. Surface/interface engineering of high-efficiency noble metal-free electrocatalysts for energy-related electrochemical reactions. Journal of Energy Chemistry, 2021, 54 : 89– 104
CrossRef ADS Google scholar
[38]
Zhao C X, Liu J N, Li B Q, Ren D, Chen X, Yu J, Zhang Q. Multiscale construction of bifunctional electrocatalysts for long-lifespan rechargeable zinc–air batteries. Advanced Functional Materials, 2020, 30( 36): 2003619
CrossRef ADS Google scholar
[39]
Ren J T, Yuan Z Y. A universal route to N-coordinated metals anchored on porous carbon nanosheets for highly efficient oxygen electrochemistry. Journal of Materials Chemistry A, 2019, 7( 22): 13591– 13601
CrossRef ADS Google scholar
[40]
Shi Y M, Zhang B. Recent advances in transition metal phosphide nanomaterials: synthesis and applications in hydrogen evolution reaction. Chemical Society Reviews, 2016, 45( 6): 1529– 1541
CrossRef ADS Google scholar
[41]
Li H, Li Q, Wen P, Williams T B, Adhikari S, Dun C C, Lu C, Itanze D, Jiang L, Carroll D L, Donati G L, Lundin P M, Qiu Y, Geyer S M. Colloidal cobalt phosphide nanocrystals as trifunctional electrocatalysts for overall water splitting powered by a zinc-air battery. Advanced Materials, 2018, 30( 9): 1705796
CrossRef ADS Google scholar
[42]
He P, Yu X Y, Lou X W. Carbon-incorporated nickel−cobalt mixed metal phosphide nanoboxes with enhanced electrocatalytic activity for oxygen evolution. Angewandte Chemie International Edition, 2017, 56( 14): 3897– 3900
CrossRef ADS Google scholar
[43]
Yan L T, Cao L, Dai P C, Gu X, Liu D D, Li L J, Wang Y, Zhao X B. Metal-organic frameworks derived nanotube of nickel−cobalt bimetal phosphides as highly efficient electrocatalysts for overall water splitting. Advanced Functional Materials, 2017, 27( 40): 1703455
CrossRef ADS Google scholar

Acknowledgements

This work was supported by the Natural Science Foundation of Shandong Province (ZR2019PB013) and the Training Program of Innovation and Entrepreneurship for Undergraduates (CXCY2021161).

Electronic Supplementary Material

Supplementary material is available in the online version of this article at https://dx.doi.org/10.1007/s11705-022-2153-3 and is accessible for authorized users.

版权

2022 Higher Education Press
PDF(3110 KB)

Accesses

Citation

Detail

段落导航
相关文章

/