%A Wei CHEN, Jinbo HE, Liang LI, %T Characterization of polybenzoxazine and its electrochemical polymerization mechanism %0 Journal Article %D 2009 %J Front. Chem. China %J Frontiers of Chemistry in China %@ 1673-3495 %R 10.1007/s11458-009-0105-9 %P 390-395 %V 4 %N 4 %U {https://journal.hep.com.cn/fcc/EN/10.1007/s11458-009-0105-9 %8 2009-12-05 %X Poly(3-(p-methyl)benzyl-3,4-dihydro-6-methyl-2H-1,3-benzoxazine) (poly(pCpT)), which was obtained from electrochemical polymerization in acetonitrile/alkali aqueous solution, was characterized by FT-IR, UV-Vis and 1H-NMR. The results indicate a ring-opening structure of the polymer. By using a rotating-ring disc electrode (RRDE), the electrochemical behaviors of polymerization were studied and the polymerization mechanism was proposed.