%A Wei CHEN, Jinbo HE, Liang LI,
%T Characterization of polybenzoxazine and its electrochemical
polymerization mechanism
%0 Journal Article
%D 2009
%J Front. Chem. China
%J Frontiers of Chemistry in China
%@ 1673-3495
%R 10.1007/s11458-009-0105-9
%P 390-395
%V 4
%N 4
%U {https://journal.hep.com.cn/fcc/EN/10.1007/s11458-009-0105-9
%8 2009-12-05
%X Poly(3-(p-methyl)benzyl-3,4-dihydro-6-methyl-2H-1,3-benzoxazine) (poly(pCpT)), which was obtained from electrochemical polymerization in acetonitrile/alkali aqueous solution, was characterized by FT-IR, UV-Vis and 1H-NMR. The results indicate a ring-opening structure of the polymer. By using a rotating-ring disc electrode (RRDE), the electrochemical behaviors of polymerization were studied and the polymerization mechanism was proposed.