Energy & Environmental Materials >

2024 , Vol. 7 >Issue 2: 12563

DOI: https://doi.org/10.1002/eem2.12563

Sustainable Furfural Biomass Feedstocks Electrooxidation toward Value-Added Furoic Acid with Energy-Saving H2 Fuel Production Using Pt-Decorated Co3O4 Nanospheres

  • Talshyn Begildayeva 1 ,
  • Jayaraman Theerthagiri 1 ,
  • Seung Jun Lee 1 ,
  • Ahreum Min 1 ,
  • Gyeong-Ah Kim 1 ,
  • Sivakumar Manickam 2 ,
  • Myong Yong Choi , 1
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  • 1. Department of Chemistry (BK21 FOUR), Core-Facility Center for Photochemistry & Nanomaterials, Research Institute of Natural Sciences, Gyeongsang National University, Jinju 52828, South Korea
  • 2. Petroleum and Chemical Engineering, Faculty of Engineering, Universiti Teknologi Brunei, Jalan Tungku Link Gadong, Bandar Seri Begawan BE1410, Brunei Darussalam
mychoi@gnu.ac.kr

Received date: 03 Oct 2022

Revised date: 17 Nov 2022

Copyright

2022 2022 The Authors. Energy & Environmental Materials published by John Wiley & Sons Australia, Ltd on behalf of Zhengzhou University.
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Abstract

Here, furfural oxidation was performed to replace the kinetically sluggish O2 evolution reaction (OER). Pt-Co3O4 nanospheres were developed via pulsed laser ablation in liquid (PLAL) in a single step for the paired electrocatalysis of an H2 evolution reaction (HER) and furfural oxidation reaction (FOR). The FOR afforded a high furfural conversion (44.2%) with a major product of 2-furoic acid after a 2-h electrolysis at 1.55 V versus reversible hydrogen electrode in a 1.0-M KOH/50-mM furfural electrolyte. The Pt-Co3O4 electrode exhibited a small overpotential of 290 mV at 10 mA cm-2. As an anode and cathode in an electrolyzer system, the Pt-Co3O4 electrocatalyst required only a small applied cell voltage of ∼1.83 V to deliver 10 mA cm-2, compared with that of the pure water electrolyzer (OER||HER, ∼1.99 V). This study simultaneously realized the integrated production of energy-saving H2 fuel at the cathode and 2-furoic acid at the anode.

Key words： biomass conversion; electrochemical furfural oxidation; overall water splitting; Pt-Co3O4 electrocatalyst; pulsed laser ablation in liquid

Cite this article

Talshyn Begildayeva , Jayaraman Theerthagiri , Seung Jun Lee , Ahreum Min , Gyeong-Ah Kim , Sivakumar Manickam , Myong Yong Choi . Sustainable Furfural Biomass Feedstocks Electrooxidation toward Value-Added Furoic Acid with Energy-Saving H2 Fuel Production Using Pt-Decorated Co3O4 Nanospheres[J]. Energy & Environmental Materials, 2024 , 7(2) : 12563 . DOI: 10.1002/eem2.12563

References

Publishing order | Descend order by publishing year | Descend order by cited within
1
H. Liu , T.-H. Lee , Y. Chen , E. W. Cochran , W. Li , ChemElectroChem. 2021, 8, 2817.

2
H. Mohammadi Khalfbadam , K. Y. Cheng , R. Sarukkalige , A. H. Kaksonen , A. S. Kayaalp , M. P. Ginige , Bioresour. Technol. 2016, 216, 529.

3
J. Theerthagiri , J. Park , H. T. Das , N. Rahamathulla , E. S. F. Cardoso , A. P. Murthy , G. Maia , D. V. N. Vo , M. Y. Choi , Environ. Chem. Lett. 2022, 20, 2929.

4
N. Jiang , X. Liu , J. Dong , B. You , X. Liu , Y. Sun , ChemNanoMat. 2017, 3, 491.

5
Y. Yu , S. J. Lee , J. Theerthagiri , Y. Lee , M. Y. Choi , Appl. Catalysis B Environ. 2022, 316, 121603.

6
J. Theerthagiri , S. J. Lee , A. P. Murthy , J. Madhavan , M. Y. Choi , Curr. Opinion Solid State Mater. Sci. 2020, 24, 100805.

7
S. J. Lee , J. Theerthagiri , P. Nithyadharseni , P. Arunachalam , D. Balaji , A. Madan Kumar , J. Madhavan , V. Mittal , M., Y. Choi , Renew. Sust. Energ. Rev. 2021, 143, 110849.

8
S. Naik Shreyanka , J. Theerthagiri , S. J. Lee , Y. Yu , M. Y. Choi , Chem. Eng. J. 2022, 446, 137045.

9
J. Theerthagiri , A. P. Murthy , S. J. Lee , K. Karuppasamy , S. R. Arumugam , Y. Yu , M. M. Hanafiah , H.-S. Kim , V. Mittal , M. Y. Choi , Ceram. Int. 2021, 47, 4404.

10
H. Zhang , B. Xi , Y. Gu , W. Chen , S. Xiong , Nano Res. 2021, 14, 3466.

11
Q. Li , C. Ma , J. Di , J. Ni , Y.-C. He , Bioresource Technol. 2022, 347, 126376.

12
T. Wang , Z. Huang , T. Liu , L. Tao , J. Tian , K. Gu , X. Wei , P. Zhou , L. Gan , S. Du , Y. Zou , R. Chen , Y. Li , X.-Z. Fu , S. Wang , Angew. Chem. Int. Ed. 2022, 61, e202115636.

13
L. Ji , Z. Tang , D. Yang , C. Ma , Y.-C. He , Bioresource Technol. 2021, 340, 125691.

14
W. Xu , C. Yu , J. Chen , Z. Liu , Appl. Catal. B Environ. 2022, 305, 121062.

15
S. Liang , L. Pan , T. Thomas , B. Zhu , C. Chen , J. Zhang , H. Shen , J. Liu , M. Yang , Chem. Eng. J. 2021, 415, 128864.

16
T. Wang , L. Tao , X. Zhu , C. Chen , W. Chen , S. Du , Y. Zhou , B. Zhou , D. Wang , C. Xie , P. Long , W. Li , Y. Wang , R. Chen , Y. Zou , X.-Z. Fu , Y. Li , X. Duan , S. Wang , Nature Catalys. 2022, 5, 66.

17
M. Ketkaew , S. Assavapanumat , S. Klinyod , A. Kuhn , C. Wattanakit , Chem. Commun. 2022, 58, 4312.

18
X. Zhang , M. Han , G. Liu , G. Wang , Y. Zhang , H. Zhang , H. Zhao , Appl. Catal. B Environ. 2019, 244, 899.

19
J. Theerthagiri , S. J. Lee , K. Karuppasamy , J. Park , Y. Yu , M. L. A. Kumari , S. Chandrasekaran , H.-S. Kim , M. Y. Choi , J. Hazard. Mater. 2021, 420, 126648.

20
J. Theerthagiri , R. A. Senthil , P. Nithyadharseni , S. J. Lee , G. Durai , P. Kuppusami , J. Madhavan , M. Y. Choi , Ceram. Int. 2020, 46, 14317.

21
J. Theerthagiri , S. J. Lee , K. Karuppasamy , S. Arulmani , S. Veeralakshmi , M. Ashokkumar , M. Y. Choi , J. Hazard. Mater. 2021, 412, 125245.

22
S. J. Lee , J. Theerthagiri , M. Y. Choi , Chem. Eng. J. 2021, 427, 130970.

23
S. H. Lee , H. J. Jung , S. J. Lee , J. Theerthagiri , T. H. Kim , M. Y. Choi , Appl. Surf. Sci. 2020, 506, 145006.

24
Y. Yu , J. Theerthagiri , S. J. Lee , G. Muthusamy , M. Ashokkumar , M. Y. Choi , Chem. Eng. J. 2021, 411, 128486.

25
Y. Yu , S. S. Naik , Y. Oh , J. Theerthagiri , S. J. Lee , M., Y. Choi , J. Hazard. Mater. 2021, 420, 126585.

26
S. Shankar Naik , S. J. Lee , Y. Yu , A. M. Al-Mohaimeed , J. Theerthagiri , M. Y. Choi , Mater. Lett. 2022, 308, 131218.

27
J. Theerthagiri , K. Karuppasamy , S. J. Lee , R. Shwetharani , H.-S. Kim , S. K. K. Pasha , M. Ashokkumar , M. Y. Choi , Light Sci. Appl. 2022, 11, 250.

28
Y. Yu , S. Jun Lee , J. Theerthagiri , S. Fonseca , L. M. C. Pinto , G. Maia , M. Yong Choi , Chem. Eng. J. 2022, 435, 134790.

29
T. Begildayeva , S. J. Lee , Y. Yu , J. Park , T. H. Kim , J. Theerthagiri , A. Ahn , H. J. Jung , M. Y. Choi , J. Hazard. Mater. 2020, 409, 124412.

30
T. Begildayeva , J. Theerthagiri , S. J. Lee , Y. Yu , M. Y. Choi , Small 2022, 18, 2204309.

31
K. Zarean Mousaabadi , A. A. Ensafi , B. Rezaei , ACS Appl. Nano Mat. 2022, 5, 8097.

32
T. Zhang , S. Zhao , C. Zhu , J. Shi , C. Su , J. Yang , M. Wang , J. Li , J. Li , P. Liu , C. Wang , Nano Res. 2022, 15, 1246.

33
V. G. Hadjiev , M. N. Iliev , I. , V. Vergilov , J. Phys. C Solid State Phys. 1988, 21, L199.

34
S. Farhadi , J. Safabakhsh , P. Zaringhadam , J. Nanostruct. Chem. 2013, 3, 69.

35
J. Zhang , J. Ma , T. S. Choksi , D. Zhou , S. Han , Y.-F. Liao , H. B. Yang , D. Liu , Z. Zeng , W. Liu , X. Sun , T. Zhang , B. Liu , J. Am. Chem. Soc. 2022, 144, 2255.

36
Z. Shi , L. Lan , Y. Li , Y. Yang , Q. Zhang , J. Wu , G. Zhang , X. Zhao , ACS Sustain. Chem. Eng. 2018, 6, 16503.

37
Y. Li , T. Chen , S. Zhao , P. Wu , Y. Chong , A. Li , Y. Zhao , G. Chen , X. Jin , Y. Qiu , D. Ye , ACS Catal. 2022, 12, 4906.

38
B. Paul , P. Bhanja , S. Sharma , Y. Yamauchi , Z. A. Alothman , Z.-L. Wang , R. Bal , A. Bhaumik , J. Colloid Interface Sci. 2021, 582, 322.

39
E. I. Vovk , A. V. Kalinkin , M. Y. Smirnov , I. O. Klembovskii , V. I. Bukhtiyarov , J. Phys. Chem. C 2017, 121, 17297.

40
Y. Takagi , H. Wang , Y. Uemura , T. Nakamura , L. Yu , O. Sekizawa , T. Uruga , M. Tada , G. Samjeské , Y. Iwasawa , T. Yokoyama , Phys. Chem. Chem. Phys. 2017, 19, 6013.

41
Z. Ren , Y. Yang , S. Wang , X. Li , H. Feng , L. Wang , Y. Li , X. Zhang , M. Wei , Appl. Catal. B Environ. 2021, 295, 120290.

42
L. Gong , N. Agrawal , A. Roman , A. Holewinski , M. J. Janik , J. Catal. 2019, 373, 322.

43
T. W. van Deelen , C. Hernández Mejía , K. P. de Jong , Nature Catalys. 2019, 2, 955.

44
Y. Wang , H. Li , Z. Yang , W. Zhang , J. Hua , J. Sep. Sci. 2017, 40, 4805.

45
R. Latsuzbaia , R. Bisselink , A. Anastasopol , H. van der Meer , R. van Heck , M. S. Yagüe , M. Zijlstra , M. Roelands , M. Crockatt , E. Goetheer , E. Giling , J. Appl. Electrochem. 2018, 48, 611.

46
B. V. Lyalin , V. A. Petrosyan , Russ. J. Electrochem. 2010, 46, 1199.

47
A. J. Motheo , G. Tremiliosi-Filho , E. R. Gonzalez , K. B. Kokoh , J. M. Léger , C. Lamy , J. Appl. Electrochem. 2006, 36, 1035.

48
Q. Tian , D. Shi , Y. Sha , Molecules 2008, 13, 948.

49
A. Moysiadou , S. Lee , C.-S. Hsu , H. M. Chen , X. Hu , J. Am. Chem. Soc. 2020, 142, 11901.

50
K. Liu , F. Wang , P. He , T. A. Shifa , Z. Wang , Z. Cheng , X. Zhan , J. He , Adv. Energy Mat. 2018, 8, 1703290.

51
A. Dutta , N. Pradhan , J. Phys. Chem. Lett. 2017, 8, 144.

52
J. Xu , J. Li , D. Xiong , B. Zhang , Y. Liu , K.-H. Wu , I. Amorim , W. Li , L. Liu , Chem. Sci. 2018, 9, 3470.

53
J. Yang , H. Liu , W. N. Martens , R. L. Frost , J. Phys. Chem. C 2010, 114, 111.

54
S. R. Kubota , K.-S. Choi , ACS Sustain. Chem. Eng. 2018, 6, 9596.

55
J. Hidalgo-Carrillo , A. Marinas , F. J. Urbano , Chemistry of Furfural and Furanic Derivatives, Vol. 2, World Scientific (Europe), Singapore 2017.

56
X. Huang , J. Song , M. Hua , B. Chen , Z. Xie , H. Liu , Z. Zhang , Q. Meng , B. Han , Chem. Sci. 2021, 12, 6342.

57
T. Begildayeva , D. Chinnadurai , S. J. Lee , Y. Yu , J. K. Song , M., Y. Choi , J. Alloys Compd. 2022, 901, 163446.

58
Y. Kwon , K. J. P. Schouten , J. C. van der Waal , E. de Jong , M. T. M. Koper , ACS Catal. 2016, 6, 6704.

59
A. S. May , E. J. Biddinger , ACS Catal. 2020, 10, 3212.

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