Energy and environmental topics are tightly linked and cannot be understood without each other especially under the stringent legislation policies and environmental social awareness. Both are considered hot scientific research topics with more than 5 million documents archived on the Web of Science until the year 2019. Based on a vast number of publications, this work proposes a bibliometrics approach to derive scientific connections and to envision future research trends based on semantic analysis and networking landscape representations. The study found that research trends have evolved from a theoretical approach to a more general point of view related to the optimization and integration of renewable energy applications. In particular, the whole energy value chain from harvesting to consumption (including distribution, storage, management and conservation) is the trendiest area of current research and especially its application to the building environment. Those research areas are strongly supported by the recent developments on the internet of things and wireless sensor networks.
Diversified human activities and inappropriate economic growth strategies have induced a trade-off between economic growth and environmental degradation worldwide. Consequently, the aggravating environmental concerns have warranted regulations to be enforced for safeguarding the welfare of the global environment. However, the effectiveness of such environmental regulations in reducing environmental deterioration has received equivocal empirical evidence in the literature. Against this backdrop, this study investigates the influence of environmental regulations on the ecological footprints in the context of the Next Eleven countries between 1990 and 2016. The results from the econometric analysis, controlling for cross-sectional dependency issues in the data, reveal that the existing environmental regulations legislated in the Next Eleven countries are ineffective in reducing the ecological footprints of these nations. Besides, greater energy consumption and openness to international trade are found to boost ecological footprints. Moreover, the Environmental Kuznets Curve hypothesis is also authenticated for the panel of the Next Eleven nations. The country-specific findings indicate that energy consumption anonymously degraded the environment in all the eleven nations, while heterogeneous impacts of environmental regulations, economic growth and international trade on the environment are ascertained. Hence, these findings, in a nutshell, recommend the Next Eleven nations to strengthen and enforce the environmental regulations, adopt sustainable economic growth policies, reduce fossil fuel dependency and participate in sustainable trade to ensure environmental sustainability.
Electricity is an indispensable building block for sustainable development. As national and international electrification measures in rural areas of Tanzania are progressing slowly, a solar-powered mini-grid system with second-life battery storage was commissioned on an island in Lake Victoria in 2019 to support local development. This article evaluates the socio-economic impacts associated with electrification through this system. On average, 42.31 kWh of electricity could be provided per day. The daily demand of the main infrastructure (hospital and school) was 18.75 kWh on average. The remaining capacity thus offers enough potential to supply private households and possible economic activities. In order to evaluate the impact of electrification, a qualitative survey was conducted on site 12 months after commissioning, with 7% of the people living there being interviewed. Language barriers as well as intercultural hurdles made the survey difficult and required an adaptation of the on-site implementation. The focus of the survey was on the areas of health, education and economics. The study revealed that the availability of electricity has enormous potential to improve people's living conditions. Initial successes could be seen, especially in the areas of health care and the economic sector. So far, electrification has had no influence on the area of education. While the connections for the main infrastructure have been institutionally supported, the system-related electricity price of €1.30/kWh has proven to be a major obstacle for private households. This is far too high for widespread use compared to incomes. The article thus focuses on the observation that full socio-economic development through electrification can only succeed if local people can afford it. Possibilities to solve this problem are analysed. Since the energy is generated on the basis of renewable resources, the analysis focuses on the use of mechanisms of the emissions trading system (ETS). The aim is to generate revenue through the sale of certified emission reductions (CERs) for the saved CO2 emissions and thus reduce the electricity price. A reference scenario of conventional energy production forms the basis for discussion of the effectiveness of the Clean Development Mechanism (CDM) and the Carbon Initiative for Development (Ci-Dev). In addition, the approach of a monthly free quota of electricity, the free basic electricity initiative (FBE), is included in the evaluation.
The use of alternative energy sources is nearly the only way to meet the energy needs of people worldwide caused by the exhaustion of natural fuel sources. Currently, solar energy is the most affordable and environmentally sustainable energy resource. However, the efficiency of the existing solar collectors is below 50%. There are many technological approaches to increase the heat transfer efficiency of solar collectors, which imply the enhancement of solar radiation uptake. The efficiency of solar collectors was also found dependent upon the properties of the working liquid. Nanofluids are used to improve the thermal properties of solar collectors as they are characterized by good radiation absorption performance. This paper examines the thermal performance of different nanofluids used to collect solar energy at the volumetric flow rate ranging from 50 to 100 ml/h using a GALMET heat exchanger. The examined nanofluids are aqueous solutions composed of Al2O3, SiO2, TiO2, and graphene nanoparticles (0.500…2wt.%). With these nanofluids, direct absorption solar collectors (DASCs) demonstrated efficiency improvements of up to 5%. The effect of flow hydrodynamics on heat transfer capacity and thermal efficiency of solar collectors has been studied. The thermal performances of nanofluids were as follows: graphene-based, 10.755 kJ/m; TiO2-based, 9.414 kJ/m2; SiO2-based, 7.467 kJ/m2; and Al2O3-based, 5.714 kJ/m2. The efficiencies of solar collectors using these nanofluids as a working fluid were 64%, 59%, 57%, and 52%, respectively. The multi-factor cluster analysis revealed that graphene nanofluid was the most efficient choice.
Recent environmental regulations have urged refiners to decrease NO x emissions related to fuels particularly used in marine transportation. To this, hydrodenitrogenation (HDN) of Iranian Vacuum Bottom (IVB), as one of the most abundant but problematic effluents of Iranian refineries used for marine applications, was evaluated for the very first time via batch hydrotreating procedure over a commercial NiMo catalyst. First, the feed material's physicochemical properties were fully analyzed using several analytic techniques such as CHNS, micro-carbon residue, and TGA. Process chemistry of the HDN and mild hydrocracking (MHC) processes was studied systematically following an L9-assisted design of experiment (Taguchi method) whereby temperature (350–410 °C), reaction time (1–3 h), oil content:catalyst ratio (1.5–2.5), and H2 initial pressure (3.0–7.0 MPa) were considered as control factors. Adding to the highly pre-pressurized medium (H2 initial pressure of 7.0 MPa) at elevated temperature (410 °C) as the most favorable condition for HDN and MHC reactions, results also highlighted a few critical interactions between the operating variables. The key was simultaneous saturation and decomposition of the highly aromatic nature of IVB, under which 65.3% of nitrogen impurities were taken out of the feed’s recalcitrant network. Notably, we took advantage of some well-known analytic techniques like Sim Dis and GC–MS to shed light on the origin of the N-containing compounds in the feed material and physicochemical characteristics of liquid products. These fuel-related analyses provided us a deeper look into the process chemistry using thermodynamic and kinetic backgrounds.
The current work deals with the process intensification of esterification reaction via ultrasonic (US) and microwave (MW) irradiations using the cheapest feedstock, such as Palm Fatty Acid Distillate (PFAD). Systematic studies have been done by conventional methods to find the optimum parameters, such as molar ratio of PFAD to methanol, temperature, type of catalyst, and catalyst loading. In order to enhance the rate of reaction, experiments were carried out using approaches based on ultrasound and microwave irradiations at optimal parameters obtained from the conventional approach. Significant enhancement in extent of equilibrium conversion and rate of reaction is observed in the presence of microwave irradiation than any other method used in the current study. The maximum reduction in acid value obtained using MW irradiation, US irradiation, and conventional approaches was 98.8% (for 25 min of reaction time), 97.8% (for 150 min of reaction time), and 97.6% (for 180 min of reaction time), respectively. The kinetic rate constants (activation energy) for the reaction using MW irradiation, US irradiation, and conventional approach were 0.7089 (9.6 × 104 kJ/mg), 0.2063 (1.7 × 105 kJ/mg), and 0.1629 (2.1 × 105 kJ/mg) l/mol/min, respectively.
Fly ash (FA) is a problematic solid waste, possessing essential elements which modifies the properties of soil and improve the plant growth. FA also contains toxic heavy metals, thus there is an urgent need to study the influence of heavy metals present in FA on the growth of plant. The present study was designed to analyze improvement in chemical composition and antioxidant defense mechanism of seed oil extracts from Jatropha curcas grown in different doses of FA (0% FA, 25% FA, 50% FA, 75% FA and 100% FA) along with garden soil (GS). A comparison of methyl esters of fatty acids was analyzed in oil extracts using gas chromatography–mass spectrometry (GC–MS). Sixteen compounds were detected, constituting 99.94% of the total oil constituents. Methyl esters of oleic acid, linoleic acid and hexadecanoic acid were the major compounds present. Comparative GC–MS analysis of the three samples showed an increase of 2.15 and 87.84-fold in 25% FA and 50% FA. The antioxidant potential was determined using 2–2′-diphenyl-1-picrylhydrazyl (DPPH) and ferric reducing potential (FRAP). Highest scavenging activity and lowest IC50 were observed in 50% FA sample followed by 25% FA and 100% GS. Activity of various antioxidant defense enzymes like SOD, CAT, POD and APX was analyzed. Treatment (50% FA with 50% GS) demonstrated enhanced chemical contents and antioxidant defense enzymes. These results suggest the utilization of FA as soil amendment for the growth of non-food crop J. curcas. altered chemical composition and antioxidative defense enzymes induced in response to FA amendment to soil reflects its suitability for phytoremediation.